SAFETY DATA SHEET

1. Identification

Product number	ID12AA
Product identifier	19 OZ HEAVY DUTY FOAMING CLNR
Revision date	05-21-2015
Company information	K-CHEM INC.
	3908 3RD AVE. S.
	BIRMINGHAM, AL 35222 United States
Company phone	General Assistance 205-592-0844
Emergency telephone US	1-800-255-3924
Emergency telephone outside	1-813-248-0585
US
Version #	04
Supersedes date	02-20-2015
Recommended use	CLEANER
Recommended restrictions	None known.

2. Hazard(s) identification

Physical hazards

Health hazards

Environmental hazards

OSHA defined hazards

Label elements

Signal word Hazard statement

Precautionary statement Prevention

Response

Storage

Disposal

Hazard(s) not otherwise classified (HNOC)

Supplemental information

Flammable aerosols Category 1

Skin corrosion/irritation Category 2

Not classified.

Not classified.

Danger

Extremely flammable aerosol. Causes skin irritation.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear protective gloves.

If on skin: Wash with plenty of water. Specific treatment (see this label). If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.

Not available.

None known.

None.

3. Composition/information on ingredients

Mixtures
Chemical name	Common name and synonyms	CAS number	%
Butane		106-97-8	2.5 - 10
Disodium Metasilicate		6834-92-0	1 - 2.5
Polyethylene Glycol Octylphenyl		9036-19-5	1 - 2.5
Ether
Propane		74-98-6	1 - 2.5
Product name: 19 OZ HEAVY DUTY FOAMING CLNR				SDS US
Product #: 1000009348 Version #: 04	Revision date: 05-21-2015 Issue date: 02-06-2015		1 / 10

Chemical name	Common name and synonyms	CAS number	%
Trisodium Phosphate		10101-89-0	1 - 2.5
2-Butoxyethanol		111-76-2	0.1 - 1
Other components below reportable levels			80 - 90

#: This substance has workplace exposure limit(s).

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.

4. First-aid measures

Inhalation

Skin contact

Eye contact

Ingestion

Most important symptoms/effects, acute and delayed

Indication of immediate medical attention and special treatment needed

General information

If inhalation of gas/fume/vapor/dust/mist from the material is excessive (air concentration is greater than the TLV or health effects are noticed), immediately remove the affected person(s) to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician or Poison Control Center immediately. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician if symptoms develop or persist.

Call a physician or Poison Control Center immediately.

Call a physician or Poison Control Center immediately.

Rinse mouth. Get medical attention if symptoms occur.

Skin irritation. May cause redness and pain.

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.

Immediate medical attention is required. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.

5. Fire-fighting measures

Suitable extinguishing media

Unsuitable extinguishing media

Specific hazards arising from the chemical

Special protective equipment and precautions for firefighters

Fire-fighting equipment/instructions

Specific methods

General fire hazards

Not available.

Do not use water jet as an extinguisher, as this will spread the fire.

Contents under pressure. Pressurized container may explode when exposed to heat or flame.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.

Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.

Extremely flammable aerosol.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

Methods and materials for containment and cleaning up

Environmental precautions

Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. If possible, turn leaking containers so that gas escapes rather than liquid. Isolate area until gas has dispersed. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Prevent entry into waterways, sewer, basements or confined areas.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.

Do not contaminate water. Avoid discharge into drains, water courses or onto the ground.

Product name: 19 OZ HEAVY DUTY FOAMING CLNR	SDS US
Product #: 1000009348 Version #: 04 Revision date: 05-21-2015 Issue date: 02-06-2015	2 / 10

7. Handling and storage

Precautions for safe handling

Conditions for safe storage, including any incompatibilities

Will ignite if exposed to intensive heat or open air. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not get this material on clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices.

Level 1 Aerosol.

Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS).

8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components	Type	Value
2-Butoxyethanol (CAS	PEL	240 mg/m3
111-76-2)
		50 ppm
Propane (CAS 74-98-6)	PEL	1800 mg/m3
		1000 ppm
US. ACGIH Threshold Limit Values
Components	Type	Value
2-Butoxyethanol (CAS	TWA	20 ppm
111-76-2)
Butane (CAS 106-97-8)	STEL	1000 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components	Type	Value
2-Butoxyethanol (CAS	TWA	24 mg/m3
111-76-2)
		5 ppm
Butane (CAS 106-97-8)	TWA	1900 mg/m3
		800 ppm
Propane (CAS 74-98-6)	TWA	1800 mg/m3
		1000 ppm

Biological limit values
ACGIH Biological Exposure Indices
Components	Value	Determinant	Specimen	Sampling Time
2-Butoxyethanol (CAS	200 mg/g	Butoxyacetic	Creatinine in	*
111-76-2)		acid (BAA),	urine
		with hydrolysis
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2)		Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2)		Skin designation applies.
US - Tennesse OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2)		Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2)		Can be absorbed through the skin.

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.

Product name: 19 OZ HEAVY DUTY FOAMING CLNR

Product #: 1000009348 Version #: 04 Revision date: 05-21-2015 Issue date: 02-06-2015

SDS US

3 / 10

Appropriate engineering controls

Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear tight-fitting goggles or face shield. Face shield is recommended. Wear safety glasses with side shields (or goggles).

Hand protection

Skin protection

Other

Skin protection

Respiratory protection

Thermal hazards

General hygiene considerations

Wear appropriate chemical resistant gloves.

Wear chemical protective equipment that is specifically recommended by the manufacturer. Use of an impervious apron is recommended. It may provide little or no thermal protection.

If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

Wear appropriate thermal protective clothing, when necessary.

When using, do not eat, drink or smoke. Do not get in eyes. Do not get this material in contact with skin. Avoid contact with skin. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties

Appearance

Physical state Gas.

Form Aerosol.

Color Not available.

Odor Not available.

Odor threshold Not available.

pH Not available.

Melting point/freezing point Not available.

Initial boiling point and boiling 212 °F (100 °C) estimated

range

Flash point -156.0 °F (-104.4 °C) Propellant estimated

Evaporation rate Not available.

Flammability (solid, gas) Not available.

Upper/lower flammability or explosive limits

Flammability limit - lower Not available.

(%)

Flammability limit - upper Not available.

(%)

Explosive limit - lower (%) Not available.

Explosive limit - upper (%) Not available.

Vapor pressure 60 psig @70F estimated

Vapor density Not available.

Relative density Not available.

Solubility(ies)

Solubility (water) Not available.

Partition coefficient Not available.

(n-octanol/water)

Auto-ignition temperature Not available.

Decomposition temperature Not available.

Viscosity Not available.

Other information

Specific gravity 0.98 estimated

Product name: 19 OZ HEAVY DUTY FOAMING CLNR

Product #: 1000009348 Version #: 04 Revision date: 05-21-2015 Issue date: 02-06-2015

SDS US

4 / 10

10. Stability and reactivity

Reactivity

Chemical stability

Possibility of hazardous reactions

Conditions to avoid

Incompatible materials

Hazardous decomposition products

The product is stable and non-reactive under normal conditions of use, storage and transport. Risk of ignition.

Hazardous polymerization does not occur.

Exposure to air. Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials.

Nitrates. Oxygen. Fluorine. Chlorine.

No hazardous decomposition products are known.

11. Toxicological information

Information on likely routes of exposure

Ingestion

Inhalation

Skin contact

Eye contact

Symptoms related to the physical, chemical and toxicological characteristics

Expected to be a low ingestion hazard. Prolonged inhalation may be harmful. Causes skin irritation.

Direct contact with eyes may cause temporary irritation. Skin irritation. May cause redness and pain.

Information on toxicological effects
Acute toxicity
Components	Species	Test Results
2-Butoxyethanol (CAS 111-76-2)
Acute
DERMAL
LD50	Guinea pig	230 ml/kg, 24 Hours
		7.3 ml/kg, 4 Days
	Rabbit	450 ml/kg, 24 Hours
		435 mg/kg, 24 Hours
		0.63 ml/kg
	Rat	> 2000 mg/kg, 24 Hours
INHALATION
LC50	Rabbit	400 ppm, 7 Hours
	Rat	450 ppm, 4 Hours
ORAL
LD100	Rabbit	695 mg/kg
LD50	Dog	> 695 mg/kg
	Guinea pig	1200 mg/kg
	Rat	530 - 2800 mg/kg
Butane (CAS 106-97-8)
Acute
INHALATION
LC50	Mouse	1237 mg/l, 120 Minutes
		52 %, 120 Minutes
	Rat	1355 mg/l
Disodium Metasilicate (CAS 6834-92-0)
Acute
DERMAL
LD50	Rat	> 5000 mg/kg, 24 Hours
Product name: 19 OZ HEAVY DUTY FOAMING CLNR
Product #: 1000009348 Version #: 04	Revision date: 05-21-2015	Issue date: 02-06-2015

SDS US

5 / 10

Respiratory or skin sensitization Respiratory sensitization Skin sensitization

Germ cell mutagenicity

Carcinogenicity

Serious eye damage/eye irritation

Skin corrosion/irritation

Components	Species	Test Results
INHALATION
LC50	Rat	> 2.06 mg/l, 4 Hours
ORAL
LD50	Mouse	661.5 - 896.3 mg/kg
	Rat	600 mg/kg
Polyethylene Glycol Octylphenyl Ether (CAS 9036-19-5)
Acute
ORAL
LD50	Rat	4190 mg/kg
Propane (CAS 74-98-6)
Acute
INHALATION
LC50	Mouse	1237 mg/l, 120 Minutes
		52 %, 120 Minutes
	Rat	1355 mg/l
		658 mg/l/4h
Trisodium Phosphate (CAS 10101-89-0)
Acute
ORAL
LD50	Rat	7400 mg/kg

* Estimates for product may be based on additional component data not shown.

Causes skin irritation. Prolonged skin contact may cause temporary irritation. Harmful in contact with eyes. Direct contact with eyes may cause temporary irritation.

Not available.

This product is not expected to cause skin sensitization.

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

IARC Monographs. Overall Evaluation of Carcinogenicity

2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Reproductive toxicity

Specific target organ toxicity - single exposure

This product is not expected to cause reproductive or developmental effects. Not classified.

Specific target organ toxicity - repeated exposure

Aspiration hazard

Chronic effects

Not classified.

Not likely, due to the form of the product.

Prolonged inhalation may be harmful. Prolonged or repeated exposure may cause lung injury.

12. Ecological information

Ecotoxicity		Components of this product are hazardous to aquatic life.
	Product		Species	Test Results
	19 OZ HEAVY DUTY FOAMING CLNR (CAS Mixture)
	Aquatic
	Fish	LC50	Fish	13176 mg/L, 96 Hours

Product name: 19 OZ HEAVY DUTY FOAMING CLNR	SDS US
Product #: 1000009348 Version #: 04 Revision date: 05-21-2015 Issue date: 02-06-2015	6 / 10

Special provisions Packaging exceptions Packaging non bulk Packaging bulk

DOT

UN number

UN proper shipping name Transport hazard class(es)

Class Subsidiary risk Label(s)

Packing group

Special precautions for user

Disposal instructions

Local disposal regulations Hazardous waste code

Waste from residues / unused products

Contaminated packaging

14. Transport information

Components		Species	Test Results
2-Butoxyethanol (CAS 111-76-2)
Aquatic
Fish	LC50	Inland silverside (Menidia beryllina)	1250 mg/l, 96 hours
Polyethylene Glycol Octylphenyl Ether (CAS 9036-19-5)
Aquatic
Fish	LC50	Rainbow trout,donaldson trout	7.2 mg/l, 96 hours
		(Oncorhynchus mykiss)

* Estimates for product may be based on additional component data not shown.

Persistence and degradability No data is available on the degradability of this product.

Bioaccumulative potential No data available.

Partition coefficient n-octanol / water (log Kow)

2-Butoxyethanol 0.83

Butane 2.89

Propane 2.36

Mobility in soil No data available.

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations

Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush.

Dispose of contents/container in accordance with local/regional/national/international regulations.

Dispose in accordance with all applicable regulations.

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.

Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).

Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers.

UN1950

Aerosols, flammable, (each not exceeding 1 L capacity)

2.1

-

2.1

Not applicable.

Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

N82

306 None None

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

IATA
UN number	UN1950
UN proper shipping name	Aerosols, flammable
Transport hazard class(es)
Class	2.1
Subsidiary risk	-
Label(s)	2.1
Packing group	Not applicable.
Product name: 19 OZ HEAVY DUTY FOAMING CLNR		SDS US
Product #: 1000009348 Version #: 04	Revision date: 05-21-2015 Issue date: 02-06-2015	7 / 10

Environmental hazards ERG Code

Special precautions for user

Other information

Passenger and cargo aircraft

Cargo aircraft only Packaging Exceptions

IMDG

UN number

UN proper shipping name Transport hazard class(es)

Class Subsidiary risk Label(s)

Packing group Environmental hazards

Marine pollutant EmS

Special precautions for user

Packaging Exceptions Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

DOT

IATA; IMDG

No.

10L

Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Allowed.

Allowed.

LTD QTY

UN1950

AEROSOLS

2.1

-

2.1

Not applicable.

No. F-D, S-U

Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

LTD QTY

Not applicable.

15. Regulatory information

US federal regulations	This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
	Standard, 29 CFR 1910.1200.
	All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Trisodium Phosphate (CAS 10101-89-0)		Listed.
SARA 304 Emergency release notification
Not regulated.
Product name: 19 OZ HEAVY DUTY FOAMING CLNR			SDS US
Product #: 1000009348 Version #: 04	Revision date: 05-21-2015	Issue date: 02-06-2015	8 / 10

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories Immediate Hazard - Yes

Delayed Hazard - No

Fire Hazard - Yes

Pressure Hazard - No

Reactivity Hazard - No

SARA 302 Extremely hazardous substance

Not listed.
SARA 311/312 Hazardous	No
chemical
SARA 313 (TRI reporting)
Chemical name	CAS number	% by wt.
1,4-Dioxane	123-91-1	0.01 - 0.1

Other federal regulations

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

Not regulated.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Safe Drinking Water Act Not regulated.

(SDWA)

US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth

defects or other reproductive harm.

US. Massachusetts RTK - Substance List

2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6)

Trisodium Phosphate (CAS 10101-89-0)

US. New Jersey Worker and Community Right-to-Know Act

2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6)

US. Pennsylvania Worker and Community Right-to-Know Law

2-Butoxyethanol (CAS 111-76-2) Butane (CAS 106-97-8) Propane (CAS 74-98-6)

Trisodium Phosphate (CAS 10101-89-0)

US. Rhode Island RTK

Butane (CAS 106-97-8)

Propane (CAS 74-98-6)

Trisodium Phosphate (CAS 10101-89-0)

US. California Proposition 65

WARNING: This product contains a chemical known to the State of California to cause cancer.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance
1,4-Dioxane (CAS 123-91-1)		Listed: January 1, 1988
International Inventories
Country(s) or region	Inventory name		On inventory (yes/no)*
Australia	Australian Inventory of Chemical Substances (AICS)		No
Canada	Domestic Substances List (DSL)		Yes
Canada	Non-Domestic Substances List (NDSL)		No
China	Inventory of Existing Chemical Substances in China (IECSC)		No
Europe	European Inventory of Existing Commercial Chemical		No
	Substances (EINECS)
Europe	European List of Notified Chemical Substances (ELINCS)		No
Japan	Inventory of Existing and New Chemical Substances (ENCS)		No
Product name: 19 OZ HEAVY DUTY FOAMING CLNR			SDS US
Product #: 1000009348 Version #: 04	Revision date: 05-21-2015	Issue date: 02-06-2015	9 / 10

Country(s) or region	Inventory name	On inventory (yes/no)*
Korea	Existing Chemicals List (ECL)	No
New Zealand	New Zealand Inventory	No
Philippines	Philippine Inventory of Chemicals and Chemical Substances	No
	(PICCS)
United States & Puerto Rico	Toxic Substances Control Act (TSCA) Inventory	Yes

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

16. Other information, including date of preparation or last revision

Issue date Revision date Version #

Disclaimer

02-06-2015

05-21-2015

04

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Product name: 19 OZ HEAVY DUTY FOAMING CLNR	SDS US
Product #: 1000009348 Version #: 04 Revision date: 05-21-2015 Issue date: 02-06-2015	10 / 10