SAFETY DATA SHEET

 

 

 

 

1. Identification

 

Product number

SO32A

Product identifier

18 OZ MR. KWIK LB 12PK

Company information

K-CHEM INC.

 

P. O. Box 530632

 

BIRMINGHAM, AL 35253 United States

Company phone

General Assistance 205-592-0844

Emergency telephone US

1-800-255-3924

Emergency telephone outside

1-813-248-0585

US

 

Version #

13

Recommended use

Not available.

Recommended restrictions

None known.


 

2. Hazard(s) identification

 

Physical hazards

 

Health hazards

 

 

 

 

 

Environmental hazards

 

OSHA defined hazards

 

Label elements

 

 

 

 

 

Signal word

 

Hazard statement

 

 

Precautionary statement Prevention

 

 

Response

 

 

 

 

 

Storage

 

Disposal

 

Hazard(s) not otherwise classified (HNOC)

 

Supplemental information


 

Gases under pressure Liquefied gas

 

Skin corrosion/irritation Category 2

 

Serious eye damage/eye irritation Category 2A

 

Germ cell mutagenicity Category 2

 

Carcinogenicity Category 1

 

Specific target organ toxicity, single exposure Category 3 narcotic effects

 

Not classified.

 

Not classified.

 

 

 

 

 

 

Danger

 

Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing genetic defects. May cause cancer.

 

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection.

 

If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. Specific treatment (see this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.

 

Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Store in a well-ventilated place.

 

Dispose of contents/container in accordance with local/regional/national/international regulations.

 

None known.

 

None.


 

 

 

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Product #: SO32A Version #: 13 Issue date: 05-21-2015

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3. Composition/information on ingredients

 

Mixtures

 

 

 

Chemical name

Common name and synonyms

CAS number

%

 

 

 

 

Trichloroethylene

 

79-01-6

90 - 100

 

 

 

 

Carbon Dioxide

 

124-38-9

1 - 2.5

 

 

 

 

Other components below reportable levels

 

 

0.01 - 0.1

 

*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.


 

4. First-aid measures

 

Inhalation

 

Skin contact

 

Eye contact

 

Ingestion

 

Most important symptoms/effects, acute and delayed

 

Indication of immediate medical attention and special treatment needed


 

Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.

 

Wash off with soap and water. Get medical attention if irritation develops and persists.

 

Rinse with water. Get medical attention if irritation develops and persists.

 

Rinse mouth. Get medical attention if symptoms occur.

 

May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

 

Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.


 

General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice

(show the label where possible). Ensure that medical personnel are aware of the material(s)

involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in

attendance.


 

5. Fire-fighting measures

 

Suitable extinguishing media

 

Unsuitable extinguishing media

 

Specific hazards arising from the chemical

 

Special protective equipment and precautions for firefighters

 

Fire-fighting equipment/instructions

 

 

Specific methods


 

Water fog. Dry chemical powder. Carbon dioxide (CO2). Use fire-extinguishing media appropriate for surrounding materials.

 

None known.

 

Contents under pressure.

 

Self-contained breathing apparatus and full protective clothing must be worn in case of fire.

 

In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.

 

Cool containers exposed to flames with water until well after the fire is out.


 

6. Accidental release measures


 

Personal precautions, protective equipment and emergency procedures

 

 

 

Methods and materials for containment and cleaning up

 

 

 

 

Environmental precautions


Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.

 

Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent product from entering drains. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS.

 

Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground.


 

 

 

 

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7. Handling and storage

 

Precautions for safe handling

 

 

 

 

 

 

 

 

Conditions for safe storage, including any incompatibilities


Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers. Avoid breathing gas. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices.

 

Level 1 Aerosol.

 

Store locked up. Contents under pressure. Do not expose to heat or store at temperatures above 120F/49C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).


 

8. Exposure controls/personal protection

 

Occupational exposure limits

 

 

 

 

 

US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)

 

 

Components

Type

 

 

Value

 

 

 

 

 

 

 

Carbon Dioxide (CAS

PEL

 

 

9000 mg/m3

124-38-9)

 

 

 

 

 

 

 

 

 

5000 ppm

 

US. OSHA Table Z-2 (29 CFR 1910.1000)

 

 

 

 

Components

Type

 

 

Value

 

 

 

 

 

 

 

Trichloroethylene (CAS

Ceiling

 

 

200 ppm

79-01-6)

 

 

 

 

 

 

TWA

 

 

100 ppm

 

US. ACGIH Threshold Limit Values

 

 

 

 

Components

Type

 

 

Value

 

 

 

 

 

 

 

Carbon Dioxide (CAS

STEL

 

 

30000 ppm

124-38-9)

 

 

 

 

 

 

TWA

 

 

5000 ppm

 

Trichloroethylene (CAS

STEL

 

 

25 ppm

79-01-6)

 

 

 

 

 

 

TWA

 

 

10 ppm

 

US. NIOSH: Pocket Guide to Chemical Hazards

 

 

 

 

Components

Type

 

 

Value

 

 

 

 

 

 

 

Carbon Dioxide (CAS

STEL

 

 

54000 mg/m3

124-38-9)

 

 

 

 

 

 

 

 

 

30000 ppm

 

 

TWA

 

 

9000 mg/m3

 

 

 

 

 

5000 ppm

 

Trichloroethylene (CAS

TWA

 

 

25 ppm

79-01-6)

 

 

 

 

Biological limit values

 

 

 

 

 

ACGIH Biological Exposure Indices

 

 

 

 

Components

Value

Determinant

Specimen

Sampling Time

 

 

 

 

 

 

 

Trichloroethylene (CAS

15 mg/l

Trichloroacetic

Urine

*

79-01-6)

 

acid

 

 

 

 

0.5 mg/l

Trichloroethano

Blood

*

 

 

 

l, without

 

 

 

 

 

hydrolysis

 

 

 

* - For sampling details, please see the source document.


 

Appropriate engineering controls


Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product.


 

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Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles).


 

Hand protection

 

Skin protection

 

Other

 

Skin protection

 

Respiratory protection

 

Thermal hazards

 

General hygiene considerations


Wear appropriate chemical resistant gloves.

 

 

Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.

 

 

If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.

 

Wear appropriate thermal protective clothing, when necessary.

 

When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.


 

9. Physical and chemical properties

 

Appearance

 

Physical state Gas.

 

Form Aerosol. Liquefied gas.

 

Color Not available.

 

Odor Not available.

 

Odor threshold Not available.

 

pH Not available.

 

Melting point/freezing point Not available.

 

Initial boiling point and boiling Not available.

 

range

 

Flash point Not available.

 

Evaporation rate Not available.

 

Flammability (solid, gas) Not available.

 

Upper/lower flammability or explosive limits

 

Flammability limit - upper 52 % estimated

 

(%)

 

Explosive limit - lower (%) Not available.

 

Explosive limit - upper (%) Not available.

 

Vapor pressure 55 - 75 psig @70F estimated

 

Vapor density Not available.

 

Relative density Not available.

 

Solubility(ies)

 

Solubility (water) Not available.

 

Partition coefficient Not available.

 

(n-octanol/water)

 

Auto-ignition temperature Not available.

 

Decomposition temperature Not available.

 

Viscosity Not available.

 

Other information

 

Specific gravity 1.454 estimated


 

10. Stability and reactivity

 

Reactivity

 

Chemical stability

 

Possibility of hazardous reactions

 

Conditions to avoid

 

Incompatible materials


 

The product is stable and non-reactive under normal conditions of use, storage and transport.

 

Material is stable under normal conditions.

 

Hazardous polymerization does not occur.

 

Contact with incompatible materials.

 

Strong oxidizing agents.


 

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Hazardous decomposition No hazardous decomposition products are known. products

 

11. Toxicological information

 

Information on likely routes of exposure

 

Ingestion Expected to be a low ingestion hazard.

 

Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be

harmful.

 

Skin contact Causes skin irritation.

 

Eye contact Causes serious eye irritation.


 

Symptoms related to the physical, chemical and toxicological characteristics


May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.


 

Information on toxicological effects

 

Acute toxicity

In high concentrations, vapors are anesthetic and may cause headache, fatigue, dizziness and

 

central nervous system effects. Narcotic effects.

 

Components

Species

Test Results

 

 

 

Trichloroethylene (CAS 79-01-6)

 

 

Acute

 

 

DERMAL

 

 

LD50

Rat

19031 mg/kg

INHALATION

 

 

LC50

Rat

12500 ppm, 4 Hours

 

 

1044 mg/l/4h

 

* Estimates for product may be based on additional component data not shown.

 

Skin corrosion/irritation Causes skin irritation.

 

Serious eye damage/eye Causes serious eye irritation.

 

irritation

 

Respiratory or skin sensitization

 

Respiratory sensitization Not available.

 

Skin sensitization This product is not expected to cause skin sensitization.

 

Germ cell mutagenicity Hazardous by WHMIS criteria. Suspected of causing genetic defects.

 

Carcinogenicity May cause cancer.

 

IARC Monographs. Overall Evaluation of Carcinogenicity

 

Trichloroethylene (CAS 79-01-6) If <1L: Consumer Commodity Carcinogenic to humans.

 

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

 

Not listed.

 

US. National Toxicology Program (NTP) Report on Carcinogens

 

Trichloroethylene (CAS 79-01-6)

Reasonably Anticipated to be a Human Carcinogen.

Reproductive toxicity

This product is not expected to cause reproductive or developmental effects.

Specific target organ toxicity - May cause drowsiness and dizziness.

single exposure

 

 

Specific target organ toxicity -

Not classified.

 

repeated exposure

 

 

Aspiration hazard

Not likely, due to the form of the product.

Chronic effects

Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.

 

12. Ecological information

 

Ecotoxicity

Harmful to aquatic life with long lasting effects.

 

 

Components

 

Species

Test Results

 

 

 

 

 

Trichloroethylene (CAS 79-01-6)

 

 

 

Aquatic

 

 

 

 

Crustacea

EC50

Daphnia

2.2 mg/L, 48 Hours

 

 

 

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Components

 

Species

Test Results

 

 

 

 

Fish

LC50

Fish

40.8933, 96 Hours

 

 

Flagfish (Jordanella floridae)

3.1 mg/l, 96 hours

 

* Estimates for product may be based on additional component data not shown.

 

Persistence and degradability No data is available on the degradability of this product.

 

Bioaccumulative potential No data available.

 

Partition coefficient n-octanol / water (log Kow)

 

Trichloroethylene 2.61

 

Mobility in soil No data available.

 

Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation

potential, endocrine disruption, global warming potential) are expected from this component.

 

13. Disposal considerations


 

Disposal instructions

 

 

 

Local disposal regulations Hazardous waste code


Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations.

 

Dispose in accordance with all applicable regulations.

 

The waste code should be assigned in discussion between the user, the producer and the waste disposal company.


 

US RCRA Hazardous Waste U List: Reference

 

Trichloroethylene (CAS 79-01-6)

U228


 

Waste from residues / unused products


Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).


 

Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.

Since emptied containers may retain product residue, follow label warnings even after container is

emptied. Do not re-use empty containers.

 

14. Transport information

 

DOT

 

UN number

UN1950

 

UN proper shipping name Aerosols, non-flammable, (each not exceeding 1 L capacity)

 

Transport hazard class(es)


 

Class Subsidiary risk Label(s)

 

Packing group

 

Special precautions for user Packaging exceptions Packaging non bulk Packaging bulk


2.2

 

-

 

2.2

 

Not applicable.

 

Read safety instructions, SDS and emergency procedures before handling. 306

 

None

 

None


 

This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.

 

IATA

 

UN number UN1950

 

UN proper shipping name Aerosols, non-flammable

 

Transport hazard class(es)


 

Class 2.2

 

Subsidiary risk -

 

Label(s) 2.2

 

Packing group Not applicable.

 

Environmental hazards No.

 

ERG Code 2L

 

Special precautions for user Read safety instructions, SDS and emergency procedures before handling.

 

Product name: 18 OZ MR. KWIK LB 12PK

 

Product #: SO32A Version #: 13 Issue date: 05-21-2015


 

 

 

 

 

 

 

 

 

 

SDS US

 

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Other information

 

Passenger and cargo aircraft

 

Cargo aircraft only Packaging Exceptions

 

IMDG

 

UN number

 

UN proper shipping name Transport hazard class(es)

 

Class Subsidiary risk Label(s)

 

Packing group Environmental hazards

 

Marine pollutant EmS

 

Special precautions for user Packaging Exceptions

 

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

 

DOT

 

 

 

 

 

 

 

 

 

 

IATA; IMDG


Allowed.

 

Allowed.

 

LTD QTY

 

UN1950

 

AEROSOLS

 

2.2

 

-

 

2.2

 

Not applicable.

 

No.

 

Not available.

 

Read safety instructions, SDS and emergency procedures before handling. LTD QTY

 

Not applicable.


 

 

 

 

 

 

 

 

 

 

 

15. Regulatory information

 

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.

All components are on the U.S. EPA TSCA Inventory List.

 

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

 

Not regulated.

 

CERCLA Hazardous Substance List (40 CFR 302.4)

 

Trichloroethylene (CAS 79-01-6) Listed.

 

SARA 304 Emergency release notification

 

Not regulated.

 

OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

 

Not listed.

 

 

 

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Superfund Amendments and Reauthorization Act of 1986 (SARA)

 

Hazard categories Immediate Hazard - Yes

Delayed Hazard - Yes

Fire Hazard - No

Pressure Hazard - Yes

Reactivity Hazard - No

 

SARA 302 Extremely hazardous substance

 

Not listed.

 

 

SARA 311/312 Hazardous

No

 

chemical

 

 

SARA 313 (TRI reporting)

 

 

Chemical name

CAS number

% by wt.

 

 

 

Trichloroethylene

79-01-6

90 - 100

 

Other federal regulations

 

Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List

 

Trichloroethylene (CAS 79-01-6)

 

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)

 

Not regulated.

 

Safe Drinking Water Act Not regulated.

 

(SDWA)

 

US state regulations

 

US. Massachusetts RTK - Substance List

 

Carbon Dioxide (CAS 124-38-9)

 

Trichloroethylene (CAS 79-01-6)

 

US. New Jersey Worker and Community Right-to-Know Act

 

Carbon Dioxide (CAS 124-38-9)

 

Trichloroethylene (CAS 79-01-6)

 

US. Pennsylvania Worker and Community Right-to-Know Law

 

Carbon Dioxide (CAS 124-38-9)

 

Trichloroethylene (CAS 79-01-6)

 

US. Rhode Island RTK

 

Trichloroethylene (CAS 79-01-6)

 

US. California Proposition 65

 

WARNING: This product contains a chemical known to the State of California to cause cancer.

 

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

 

Trichloroethylene (CAS 79-01-6) Listed: April 1, 1988

 

International Inventories

 

 

Country(s) or region

Inventory name

On inventory (yes/no)*

Australia

Australian Inventory of Chemical Substances (AICS)

Yes

Canada

Domestic Substances List (DSL)

Yes

Canada

Non-Domestic Substances List (NDSL)

No

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical

Yes

 

Substances (EINECS)

 

Europe

European List of Notified Chemical Substances (ELINCS)

No

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances

Yes

 

(PICCS)

 

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes

 

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

 

A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s).

 

 

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16. Other information, including date of preparation or last revision


 

Issue date Version #

 

Disclaimer


05-21-2015

 

13

 

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.


 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

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